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Determination of solubility parameters of ionic liquids and ionic liquid/solvent mixtures from intrinsic viscosity

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Determination of solubility parameters of ionic liquids and ionic liquid/solvent mixtures from intrinsic viscosity
นักวิจัย : Weerachanchai, Piyarat , Wong, Yuewen , Lim, Kok Hwa , Tan, Timothy Thatt Yang , Lee, Jong-Min
คำค้น : DRNTU::Science::Chemistry
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2557
อ้างอิง : Weerachanchai, P., Wong, Y., Lim, K. H., Tan, T. T. Y., & Lee, J.-M. (2014). Determination of solubility parameters of ionic liquids and ionic liquid/solvent mixtures from intrinsic viscosity. ChemPhysChem, 15(16), 3580–3591. , 1439-4235 , http://hdl.handle.net/10220/24685 , http://dx.doi.org/10.1002/cphc.201402345
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : ChemPhysChem
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

The total and partial solubility parameters (dispersion, polar and hydrogen-bonding solubility parameters) of ten ionic liquids were determined. Intrinsic viscosity approaches were used that encompassed a one-dimensional method (1D-Method), and two different three-dimensional methods (3D-Method1 and 3D-Method2). The effect of solvent type, the dimethylacetamide (DMA) fraction in the ionic liquid, and dissolution temperature on solubility parameters were also investigated. For all types of effect, both the 1D-Method and 3D-Method2 present the same trend in the total solubility parameter. The partial solubility parameters are influenced by the cation and anion of the ionic liquid. Considering the effect on partial solubility parameters of the solvent type in the ionic liquid, it was observed that in both 3D methods, the dispersion and polar parameters of a 1-ethyl-3-methylimidazolium acetate/solvent (60:40 vol %) mixture tend to increase as the total solubility parameter of the solvent increases.

บรรณานุกรม :
Weerachanchai, Piyarat , Wong, Yuewen , Lim, Kok Hwa , Tan, Timothy Thatt Yang , Lee, Jong-Min . (2557). Determination of solubility parameters of ionic liquids and ionic liquid/solvent mixtures from intrinsic viscosity.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Weerachanchai, Piyarat , Wong, Yuewen , Lim, Kok Hwa , Tan, Timothy Thatt Yang , Lee, Jong-Min . 2557. "Determination of solubility parameters of ionic liquids and ionic liquid/solvent mixtures from intrinsic viscosity".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Weerachanchai, Piyarat , Wong, Yuewen , Lim, Kok Hwa , Tan, Timothy Thatt Yang , Lee, Jong-Min . "Determination of solubility parameters of ionic liquids and ionic liquid/solvent mixtures from intrinsic viscosity."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2557. Print.
Weerachanchai, Piyarat , Wong, Yuewen , Lim, Kok Hwa , Tan, Timothy Thatt Yang , Lee, Jong-Min . Determination of solubility parameters of ionic liquids and ionic liquid/solvent mixtures from intrinsic viscosity. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2557.