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Structurally characterized normal and abnormal N-heterocyclic carbene based palladium and gold complexes and their catalysis.

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Structurally characterized normal and abnormal N-heterocyclic carbene based palladium and gold complexes and their catalysis.
นักวิจัย : Xu, Xiangya.
คำค้น : DRNTU::Science::Chemistry::Organic chemistry::Heterocyclic compounds.
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2554
อ้างอิง : Xu, X. Y. (2011). Structurally characterized normal and abnormal N-heterocyclic carbene based palladium and gold complexes and their catalysis. Doctoral thesis, Nanyang Technological University, Singapore. , http://hdl.handle.net/10356/46226
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : -
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

N-heterocyclic carbenes (NHCs) have been extensively investigated and widely used as more efficient ligands. The experimental and theoretical evidences showed that C4 or C5-bound NHCs (aNHCs) are stronger donor ligands than C2-bound NHCs (nNHCs). It is expected that the outstanding strong donor abilities of aNHCs have a great influence on catalysis. However the synthesis and catalytic activity of M-aNHC complexes have not been thoroughly investigated till now compared to those of M-nNHC complexes. The objectives of this thesis were to investigate that the aNHCs ligands in catalysis either using in situ generation system or well-defined M-aNHC complexes.

บรรณานุกรม :
Xu, Xiangya. . (2554). Structurally characterized normal and abnormal N-heterocyclic carbene based palladium and gold complexes and their catalysis..
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Xu, Xiangya. . 2554. "Structurally characterized normal and abnormal N-heterocyclic carbene based palladium and gold complexes and their catalysis.".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Xu, Xiangya. . "Structurally characterized normal and abnormal N-heterocyclic carbene based palladium and gold complexes and their catalysis.."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2554. Print.
Xu, Xiangya. . Structurally characterized normal and abnormal N-heterocyclic carbene based palladium and gold complexes and their catalysis.. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2554.