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Arenedisulfonate-4d–4f 3D heterometallic coordination polymers constructed from 2,7-naphthalenedisulfonate and isonicotinic acid : structure, luminescence, and magnetic properties

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Arenedisulfonate-4d–4f 3D heterometallic coordination polymers constructed from 2,7-naphthalenedisulfonate and isonicotinic acid : structure, luminescence, and magnetic properties
นักวิจัย : Xie, Wei-Ping , Wang, Ning , Long, Yi , Ran, Xing-Rui , Gao, Jin-Ying , Chen, Chu-Jun , Yue, Shan-Tang , Cai, Yue-Peng
คำค้น : DRNTU::Engineering::Chemical engineering::Polymers and polymer manufacture
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2557
อ้างอิง : Xie, W.-P., Wang, N., Long, Y., Ran, X.-R., Gao, J.-Y., Chen, C.-J., et al. (2014). Arenedisulfonate-4d–4f 3D heterometallic coordination polymers constructed from 2,7-naphthalenedisulfonate and isonicotinic acid: Structure, luminescence, and magnetic properties. Inorganic Chemistry Communications, 40, 151-156. , 1387-7003 , http://hdl.handle.net/10220/20259 , http://dx.doi.org/10.1016/j.inoche.2013.11.029
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Inorganic chemistry communications
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

The first example of 3D heterometallic 4d–4f 2,7-naphthanlenedisulfonate compounds [LnAg2(2,7-NDS)(IN)3] (Ln=Sm (1), Eu (2), Gd (3), Tb (4), Dy(5); 2,7-NDS=2,7-naphthanlenedisulfonate; IN=isonicotinic acid) has been synthesized via hydrothermal reaction and characterized by single crystal X-ray diffraction, elemental analyses, FT-IR spectroscopy, powder X-ray diffraction(PXRD) and thermogravimetric analyses (TGA). X-Ray structural analysis reveals that compounds 1–5 exhibit same well-organized 3D coordination frameworks that are built up by 2D elliptical cylinder shaped [LnAg2(2,7-NDS)(IN)3] layers which are constructed by 1D anionic chains [Ln(2,7-NDS)(IN)3]2− linking the adjacent Ag(I) ions, and [LnAg(μ2-O)2] units, possessing a 7-connected topology with the Schläfli symbol of {33;411;56;6}. Furthermore, the luminescence properties of compounds 2 and 4 and the magnetic properties of compounds 3 and 5 were investigated.

บรรณานุกรม :
Xie, Wei-Ping , Wang, Ning , Long, Yi , Ran, Xing-Rui , Gao, Jin-Ying , Chen, Chu-Jun , Yue, Shan-Tang , Cai, Yue-Peng . (2557). Arenedisulfonate-4d–4f 3D heterometallic coordination polymers constructed from 2,7-naphthalenedisulfonate and isonicotinic acid : structure, luminescence, and magnetic properties.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Xie, Wei-Ping , Wang, Ning , Long, Yi , Ran, Xing-Rui , Gao, Jin-Ying , Chen, Chu-Jun , Yue, Shan-Tang , Cai, Yue-Peng . 2557. "Arenedisulfonate-4d–4f 3D heterometallic coordination polymers constructed from 2,7-naphthalenedisulfonate and isonicotinic acid : structure, luminescence, and magnetic properties".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Xie, Wei-Ping , Wang, Ning , Long, Yi , Ran, Xing-Rui , Gao, Jin-Ying , Chen, Chu-Jun , Yue, Shan-Tang , Cai, Yue-Peng . "Arenedisulfonate-4d–4f 3D heterometallic coordination polymers constructed from 2,7-naphthalenedisulfonate and isonicotinic acid : structure, luminescence, and magnetic properties."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2557. Print.
Xie, Wei-Ping , Wang, Ning , Long, Yi , Ran, Xing-Rui , Gao, Jin-Ying , Chen, Chu-Jun , Yue, Shan-Tang , Cai, Yue-Peng . Arenedisulfonate-4d–4f 3D heterometallic coordination polymers constructed from 2,7-naphthalenedisulfonate and isonicotinic acid : structure, luminescence, and magnetic properties. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2557.