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Enhanced charge transport properties of dye-sensitized solar cells using TiNxOy nanostructure composite photoanode

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Enhanced charge transport properties of dye-sensitized solar cells using TiNxOy nanostructure composite photoanode
นักวิจัย : Lim, Chiew Keat , Huang, Hui , Chow, Chee Lap , Tan, Pei Yun , Chen, Xiaofeng , Tse, Man Siu , Tan, Ooi Kiang
คำค้น : DRNTU::Engineering::Electrical and electronic engineering::Optics, optoelectronics, photonics.
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : Lim, C. K., Huang, H., Chow, C. L., Tan, P. Y., Chen, X., Tse, M. S., et al. (2012). Enhanced charge transport properties of dye-sensitized solar cells using TiNxOy nanostructure composite photoanode. The journal of physical chemistry C, 116(37), 19659-19664. , http://hdl.handle.net/10220/17088 , http://dx.doi.org/10.1021/jp304387c
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : The journal of physical chemistry C
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

In this Article, the improvement in the conversion efficiencies of dye-sensitized solar cells (DSSCs) was observed by integrating a small amount of thermally oxidized titanium nitride (TiNxOy) particles into the hydrothermally growth TiO2 nanoparticles to form the composite photoanode. The oxidation of titanium nitride (TiN) to TiNxOy (N-doped TiO2) was achieved using a simple single-step annealing process at 450 °C for 1 h. The existence of the O–Ti–N linkage in TiNxOy was verified using X-ray photoemission spectroscopy (XPS). The DSSCs using the composite photoanode with 5 wt % of TiNxOy particles in TiO2 showed optimum conversion efficiency with a 25.6% improvement over the conventional DSSCs using only the mesoporous TiO2 layer as photoanode. Higher incident photon-current conversion efficiency (IPCE) values were also obtained for these composite photoanodes. This marked improvement was attributed to the combined synergetic effects of an extra absorption in the visible region and an enhanced efficiency in the electron transport. The extra absorption region at 400–500 nm for TiNxOy was observed using a UV–vis spectrophotometer. In addition, the reduction of charge transport resistance in the composite photoanode as verified using electrochemical impedance spectroscopy (EIS) has also contributed to faster electron transport through the interpenetrating oxide layer.

บรรณานุกรม :
Lim, Chiew Keat , Huang, Hui , Chow, Chee Lap , Tan, Pei Yun , Chen, Xiaofeng , Tse, Man Siu , Tan, Ooi Kiang . (2555). Enhanced charge transport properties of dye-sensitized solar cells using TiNxOy nanostructure composite photoanode.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Lim, Chiew Keat , Huang, Hui , Chow, Chee Lap , Tan, Pei Yun , Chen, Xiaofeng , Tse, Man Siu , Tan, Ooi Kiang . 2555. "Enhanced charge transport properties of dye-sensitized solar cells using TiNxOy nanostructure composite photoanode".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Lim, Chiew Keat , Huang, Hui , Chow, Chee Lap , Tan, Pei Yun , Chen, Xiaofeng , Tse, Man Siu , Tan, Ooi Kiang . "Enhanced charge transport properties of dye-sensitized solar cells using TiNxOy nanostructure composite photoanode."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Lim, Chiew Keat , Huang, Hui , Chow, Chee Lap , Tan, Pei Yun , Chen, Xiaofeng , Tse, Man Siu , Tan, Ooi Kiang . Enhanced charge transport properties of dye-sensitized solar cells using TiNxOy nanostructure composite photoanode. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.