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Bond order resolved 3d 5/2 and valence band chemical shifts of Ag surfaces and nanoclusters

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Bond order resolved 3d 5/2 and valence band chemical shifts of Ag surfaces and nanoclusters
นักวิจัย : Qin, Wei , Wang, Yan , Huang, Yongli , Zhou, Zhaofeng , Yang, Chao , Sun, Changqing
คำค้น : DRNTU::Science::Chemistry::Physical chemistry.
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : Qin, W., Wang, Y., Huang, Y., Zhou, Z., Yang, C., & Sun, C. (2012). Bond order resolved 3d 5/2 and valence band chemical shifts of Ag surfaces and nanoclusters. The journal of physical chemistry A, 116(30), 7892-7897. , http://hdl.handle.net/10220/17161 , http://dx.doi.org/10.1021/jp304366z
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : The journal of physical chemistry A
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

Incorporating the tight-binding theory and the bond order–length–strength (BOLS) correlation into the X-ray photoelectron spectra of Ag(111) and (100) surfaces and the Auger electron spectra of Ag nanoparticles deposited on Al2O3 and CeO2 substrates has led to quantitative information of the 3d5/2 and the valence binding energies of an isolated Ag atom and their shifts upon bulk, defect, surface, and nanocrystal formation. It is clarified that the globally positive energy shifts originate from the undercoordination-induced Goldschmidt–Pauling bond contraction and the associated local quantum entrapment and the heterocoordination-induced bond nature alteration at the particle–substrate interfaces. Perturbation to the Hamiltonian by atomic ill-coordination dictates the energy shift that is proportional to the bond energy at equilibrium. Theoretical reproduction of the measured spectroscopic data derived that the 3d5/2 energy of an isolated Ag atom shifts from 363.02 to 367.65 eV and the valence band center from 0.36 to 8.32 eV upon bulk formation. The extended Wagner plots revealed the coefficients of valence recharging and potential screening to be 1.21 and 1.56 for Ag interacting with Al2O3 substrate and 1.15 and 1.50 for Ag with CeO2, respectively. Exercises exemplify the enhanced capabilities of XPS and AES in determining quantitative information regarding the evolution of the local bond length, bond energy, binding energy density, and atomic cohesive energy, with the coordination and chemical environment.

บรรณานุกรม :
Qin, Wei , Wang, Yan , Huang, Yongli , Zhou, Zhaofeng , Yang, Chao , Sun, Changqing . (2555). Bond order resolved 3d 5/2 and valence band chemical shifts of Ag surfaces and nanoclusters.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Qin, Wei , Wang, Yan , Huang, Yongli , Zhou, Zhaofeng , Yang, Chao , Sun, Changqing . 2555. "Bond order resolved 3d 5/2 and valence band chemical shifts of Ag surfaces and nanoclusters".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Qin, Wei , Wang, Yan , Huang, Yongli , Zhou, Zhaofeng , Yang, Chao , Sun, Changqing . "Bond order resolved 3d 5/2 and valence band chemical shifts of Ag surfaces and nanoclusters."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Qin, Wei , Wang, Yan , Huang, Yongli , Zhou, Zhaofeng , Yang, Chao , Sun, Changqing . Bond order resolved 3d 5/2 and valence band chemical shifts of Ag surfaces and nanoclusters. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.