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Assembly of two new Mn(II) coordination polymers based on 5-aminoisophthalate : structural diversity and properties

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Assembly of two new Mn(II) coordination polymers based on 5-aminoisophthalate : structural diversity and properties
นักวิจัย : Yin, Xia , Xiao, Tian-Tian , Fan, Jun , Zheng, Sheng-Run , Wang, Ning , Cai, Song-Liang , Tan, Jing-Bo , Zhang, Wei-Guang
คำค้น : -
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : Yin, X., Xiao, T.-T., Fan, J., Zheng, S.-R., Wang, N., Cai, S.-L., et al. (2012). Assembly of two new Mn(II) coordination polymers based on 5-aminoisophthalate: Structural diversity and properties. Inorganic Chemistry Communications, 22, 93-97. , 1387-7003 , http://hdl.handle.net/10220/11498 , http://dx.doi.org/10.1016/j.inoche.2012.05.031
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Inorganic chemistry communications
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

Two new Mn(II) coordination polymers, namely, [Mn(Haip)2(H2O)2] (1), and [Mn2(aip)2(bpy)]·3H2O (2) were obtained under hydrothermal conditions (aip = 5-aminoisophthalate; bpy = 2, 2′-bipyridine). Compound 1 features a 1D loop-like chain structure, and complex 2 possesses an interesting (3, 5)-connected 2-nodal 3D architecture with the Schläfli symbol of (4.62)(4.67.82), which is constructed from helical chains. Coordination modes of H2aip molecules and coligands have significant effect on the structures of the resulting complexes. Moreover, variable-temperature magnetic susceptibility measurement of complex 2 exhibits antiferromagnetic interactions between nearest Mn(II) ions with J = − 0.88(5) cm− 1 and g = 2.04(3).

บรรณานุกรม :
Yin, Xia , Xiao, Tian-Tian , Fan, Jun , Zheng, Sheng-Run , Wang, Ning , Cai, Song-Liang , Tan, Jing-Bo , Zhang, Wei-Guang . (2555). Assembly of two new Mn(II) coordination polymers based on 5-aminoisophthalate : structural diversity and properties.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Yin, Xia , Xiao, Tian-Tian , Fan, Jun , Zheng, Sheng-Run , Wang, Ning , Cai, Song-Liang , Tan, Jing-Bo , Zhang, Wei-Guang . 2555. "Assembly of two new Mn(II) coordination polymers based on 5-aminoisophthalate : structural diversity and properties".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Yin, Xia , Xiao, Tian-Tian , Fan, Jun , Zheng, Sheng-Run , Wang, Ning , Cai, Song-Liang , Tan, Jing-Bo , Zhang, Wei-Guang . "Assembly of two new Mn(II) coordination polymers based on 5-aminoisophthalate : structural diversity and properties."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Yin, Xia , Xiao, Tian-Tian , Fan, Jun , Zheng, Sheng-Run , Wang, Ning , Cai, Song-Liang , Tan, Jing-Bo , Zhang, Wei-Guang . Assembly of two new Mn(II) coordination polymers based on 5-aminoisophthalate : structural diversity and properties. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.