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Nitrogen-sensitized dual phase titanate/titania for visible-light driven phenol degradation

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Nitrogen-sensitized dual phase titanate/titania for visible-light driven phenol degradation
นักวิจัย : Cheng, Yu Hua , Subramaniam, Vishnu-Priya , Gong, Dangguo , Tang, Yuxin , Highfield, James , Pehkonen, Simo Olavi , Pichat, Pierre , Schreyer, Martin K. , Chen, Zhong
คำค้น : -
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : Cheng, Y. H., Subramaniam, V.-P., Gong, D., Tang, Y., Highfield, J., Pehkonen, S. O., et al. (2012). Nitrogen-sensitized dual phase titanate/titania for visible-light driven phenol degradation. Journal of solid state chemistry, 196, 518-527. , 0022-4596 , http://hdl.handle.net/10220/11274 , http://dx.doi.org/10.1016/j.jssc.2012.07.011
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Journal of solid state chemistry
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

A dual-phase material (DP-160) comprising hydrated titanate (H2Ti3O7·xH2O) and anatase (TiO2) was synthesized in a low-temperature one-pot process in the presence of triethylamine (TEA) as the N-source. The unique structure exhibits strong visible light absorption. The chromophore is linked to Ti–N bonds derived from both surface sensitization and sub-surface (bulk) doping. From transmission electron microscope (TEM) and textural studies by N2 physisorption, the composite exists as mesoporous particles with a grain size of ∼20 nm and mean pore diameter of 3.5 nm, responsible for the high surface area (∼180 m2/g). DP-160 demonstrated photocatalytic activity in the degradation of phenol under visible light (λ>420 nm). The activity of the composite was further enhanced by a small addition (0.001 M) of H2O2, which also gave rise to some visible light activity in the control samples. This effect is believed to be associated with the surface peroxo-titanate complex. GC–MS analyses showed that the intermediate products of phenol degradation induced by visible light irradiation of DP-160 did not differ from those obtained by UV (band-gap) irradiation of TiO2. The overall performance of the composite is attributed to efficient excitation via inter-band states (due to N-doping), surface sensitization, improved adsorptive properties of aromatic compounds due to the N-carbonaceous overlayer, and the presence of heterojunctions that are known to promote directional charge transfer in other mixed-phase titanias like Degussa P25.

บรรณานุกรม :
Cheng, Yu Hua , Subramaniam, Vishnu-Priya , Gong, Dangguo , Tang, Yuxin , Highfield, James , Pehkonen, Simo Olavi , Pichat, Pierre , Schreyer, Martin K. , Chen, Zhong . (2555). Nitrogen-sensitized dual phase titanate/titania for visible-light driven phenol degradation.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Cheng, Yu Hua , Subramaniam, Vishnu-Priya , Gong, Dangguo , Tang, Yuxin , Highfield, James , Pehkonen, Simo Olavi , Pichat, Pierre , Schreyer, Martin K. , Chen, Zhong . 2555. "Nitrogen-sensitized dual phase titanate/titania for visible-light driven phenol degradation".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Cheng, Yu Hua , Subramaniam, Vishnu-Priya , Gong, Dangguo , Tang, Yuxin , Highfield, James , Pehkonen, Simo Olavi , Pichat, Pierre , Schreyer, Martin K. , Chen, Zhong . "Nitrogen-sensitized dual phase titanate/titania for visible-light driven phenol degradation."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Cheng, Yu Hua , Subramaniam, Vishnu-Priya , Gong, Dangguo , Tang, Yuxin , Highfield, James , Pehkonen, Simo Olavi , Pichat, Pierre , Schreyer, Martin K. , Chen, Zhong . Nitrogen-sensitized dual phase titanate/titania for visible-light driven phenol degradation. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.