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Investigation of local structure effect and X-ray absorption characteristics (EXAFS) of Fe (Ti) K-edge on photocatalyst properties of SrTi(1−x)FexO(3−δ)

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Investigation of local structure effect and X-ray absorption characteristics (EXAFS) of Fe (Ti) K-edge on photocatalyst properties of SrTi(1−x)FexO(3−δ)
นักวิจัย : Ghaffari, Mohammad , Liu, T. , Huang, H. , Tan, Ooi Kiang , Shannon, Mark
คำค้น : DRNTU::Engineering::Electrical and electronic engineering.
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : http://hdl.handle.net/10220/11194 , http://dx.doi.org/10.1016/j.matchemphys.2012.06.037
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Materials chemistry and physics
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

In this study, the STFx photocatalyst powder was synthesized with a high temperature solid state reaction. The microstructures and surface of samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The electronic properties and local structure of the perovskite STFx (0 ≤ x ≤ 1) systems were probed by extended X-ray absorption fine structure (EXAFS) spectroscopy. The XPS results revealed that with increasing iron doping, the amount of Fe3+ and Fe4+ increased significantly. The X-ray absorption data are discussed in detail with respect to the Fe (Ti) K-edge. The substitution of iron by titanium increased the Ti (Fe)–O first shell disorder factors that can be explained by increasing the oxygen vacancies. Oxygen vacancies or defects act as electron traps, which could capture the photo induced electrons and thus could effectively inhibit the recombination of the photo induced electrons and holes. Moreover due to the substitution of Ti with Fe, lattice shrinkage was observed and the largest derivation from the Gaussian distribution in STFx was from those samples with x = 0.6 and x = 0.8. The substitution of iron by titanium increased the iron valence state, hence the formation of the Jahn–Teller Fe4+ ion. With increasing iron dopant the [Ti(Fe)–O]ave decreased and bond length of [Ti–O] and the consequent [Ti–O–Ti] increased and this phenomenon affected the photocatalyst and photo degradation properties of material and also decreased its efficiency.

บรรณานุกรม :
Ghaffari, Mohammad , Liu, T. , Huang, H. , Tan, Ooi Kiang , Shannon, Mark . (2555). Investigation of local structure effect and X-ray absorption characteristics (EXAFS) of Fe (Ti) K-edge on photocatalyst properties of SrTi(1−x)FexO(3−δ).
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Ghaffari, Mohammad , Liu, T. , Huang, H. , Tan, Ooi Kiang , Shannon, Mark . 2555. "Investigation of local structure effect and X-ray absorption characteristics (EXAFS) of Fe (Ti) K-edge on photocatalyst properties of SrTi(1−x)FexO(3−δ)".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Ghaffari, Mohammad , Liu, T. , Huang, H. , Tan, Ooi Kiang , Shannon, Mark . "Investigation of local structure effect and X-ray absorption characteristics (EXAFS) of Fe (Ti) K-edge on photocatalyst properties of SrTi(1−x)FexO(3−δ)."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Ghaffari, Mohammad , Liu, T. , Huang, H. , Tan, Ooi Kiang , Shannon, Mark . Investigation of local structure effect and X-ray absorption characteristics (EXAFS) of Fe (Ti) K-edge on photocatalyst properties of SrTi(1−x)FexO(3−δ). กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.