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Correlation between the band gap, elastic modulus, Raman shift and melting point of CdS, ZnS, and CdSe semiconductors and their size dependency

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Correlation between the band gap, elastic modulus, Raman shift and melting point of CdS, ZnS, and CdSe semiconductors and their size dependency
นักวิจัย : Yang, C. , Zhou, Zhaofeng , Li, J. W. , Yang, X. X. , Qin, W. , Jiang, R. , Guo, N. G. , Wang, Y. , Sun, Changqing
คำค้น : DRNTU::Engineering::Electrical and electronic engineering.
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : Yang, C., Zhou, Z. F., Li, J. W., Yang, X. X., Qin, W., Jiang, R., et al. (2012). Correlation between the band gap, elastic modulus, Raman shift and melting point of CdS, ZnS, and CdSe semiconductors and their size dependency. Nanoscale, 4(4), 1304-1307. , 2040-3364 , http://hdl.handle.net/10220/10745 , http://dx.doi.org/10.1039/c2nr11605g
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Nanoscale
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

With structural miniaturization down to the nanoscale, the detectable quantities of solid materials no longer remain constant but become tunable. For the II–VI semiconductors example, the band gap expands, the elastic modulus increases, the melting point drops, and the Raman optical phonons experience red shift associated with creation of low frequency Raman acoustic modes that undergo blue shift with decreasing the dimensional scale. In order to understand the common origin of the size dependency of these seemingly irrelevant properties, we formulated these quantities for CdS, ZnS, and CdSe semiconductors from the perspectives of bond order–length–strength correlation and the local bond averaging approach. Consistency between the theory predictions and the measured size dependence of these quantities clarified that the undercoordination-induced local strain and quantum entrapment and the varied fraction of undercoordinated atoms of the entire solid correlate these quantities and dominate their size effect.

บรรณานุกรม :
Yang, C. , Zhou, Zhaofeng , Li, J. W. , Yang, X. X. , Qin, W. , Jiang, R. , Guo, N. G. , Wang, Y. , Sun, Changqing . (2555). Correlation between the band gap, elastic modulus, Raman shift and melting point of CdS, ZnS, and CdSe semiconductors and their size dependency.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Yang, C. , Zhou, Zhaofeng , Li, J. W. , Yang, X. X. , Qin, W. , Jiang, R. , Guo, N. G. , Wang, Y. , Sun, Changqing . 2555. "Correlation between the band gap, elastic modulus, Raman shift and melting point of CdS, ZnS, and CdSe semiconductors and their size dependency".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Yang, C. , Zhou, Zhaofeng , Li, J. W. , Yang, X. X. , Qin, W. , Jiang, R. , Guo, N. G. , Wang, Y. , Sun, Changqing . "Correlation between the band gap, elastic modulus, Raman shift and melting point of CdS, ZnS, and CdSe semiconductors and their size dependency."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Yang, C. , Zhou, Zhaofeng , Li, J. W. , Yang, X. X. , Qin, W. , Jiang, R. , Guo, N. G. , Wang, Y. , Sun, Changqing . Correlation between the band gap, elastic modulus, Raman shift and melting point of CdS, ZnS, and CdSe semiconductors and their size dependency. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.