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Nickel-complexes with a mixed-donor ligand for photocatalytic hydrogen evolution from aqueous solutions under visible light

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : Nickel-complexes with a mixed-donor ligand for photocatalytic hydrogen evolution from aqueous solutions under visible light
นักวิจัย : Han, Jianyu , Zhang, Wei , Zhou, Tianhua , Wang, Xin , Xu, Rong
คำค้น : -
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2555
อ้างอิง : Han, J., Zhang, W., Zhou, T., Wang, X., & Xu, R. (2012). Nickel-complexes with a mixed-donor ligand for photocatalytic hydrogen evolution from aqueous solutions under visible light. RSC Advances, 2(22), 8293-8296. , 2046-2069 , http://hdl.handle.net/10220/10564 , http://dx.doi.org/10.1039/c2ra21422a
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : RSC advances
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

Increasing interest has been paid to the development of earth-abundant photocatalyst systems for production of hydrogen from water. In this work, we, for the first time, investigated the photocatalytic activities of complexes formed between β-mecaptoethylamine (L) and Ni(II), NiL2, and the trinuclear complex, Ni(NiL2)22+, with a mixed S and N donor environment. Both complexes were found to be active catalysts for hydrogen evolution in aqueous solutions. In particular, a high quantum efficiency of 30.9 % at 480 nm was obtained over NiL2 when Erythrosin yellowish was used as the photosensitizer.

บรรณานุกรม :
Han, Jianyu , Zhang, Wei , Zhou, Tianhua , Wang, Xin , Xu, Rong . (2555). Nickel-complexes with a mixed-donor ligand for photocatalytic hydrogen evolution from aqueous solutions under visible light.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Han, Jianyu , Zhang, Wei , Zhou, Tianhua , Wang, Xin , Xu, Rong . 2555. "Nickel-complexes with a mixed-donor ligand for photocatalytic hydrogen evolution from aqueous solutions under visible light".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Han, Jianyu , Zhang, Wei , Zhou, Tianhua , Wang, Xin , Xu, Rong . "Nickel-complexes with a mixed-donor ligand for photocatalytic hydrogen evolution from aqueous solutions under visible light."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2555. Print.
Han, Jianyu , Zhang, Wei , Zhou, Tianhua , Wang, Xin , Xu, Rong . Nickel-complexes with a mixed-donor ligand for photocatalytic hydrogen evolution from aqueous solutions under visible light. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2555.