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A rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2 and H2 uptake capability

หน่วยงาน Nanyang Technological University, Singapore

รายละเอียด

ชื่อเรื่อง : A rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2 and H2 uptake capability
นักวิจัย : Wang, Xiao-Jun , Li, Pei-Zhou , Chen, Yifei , Zhang, Quan , Zhang, Huacheng , Chan, Xiu Xiang , Ganguly, Rakesh , Li, Yongxin , Jiang, Jianwen , Zhao, Yanli
คำค้น : DRNTU::Science::Chemistry::Analytical chemistry::Gas analysis.
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2556
อ้างอิง : Wang, X. J., Li, P. Z., Chen, Y., Zhang, Q., Zhang, H., Chan, X. X., et al. (2013). A Rationally Designed Nitrogen-Rich Metal-Organic Framework and Its Exceptionally High CO2 and H2 Uptake Capability. Scientific Reports 3, 1149. , http://hdl.handle.net/10220/10003 , http://dx.doi.org/10.1038/srep01149
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Scientific reports
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

On the way towards a sustainable low-carbon future, the design and construction of chemical or physical adsorbents for CO2 capture and clean energy storage are vital technology. The incorporation of accessible nitrogen-donor sites into the pore walls of porous adsorbents can dramatically affect the CO2 uptake capacity and selectivity on account of the dipole-quadrupole interactions between the polarizable CO2 molecule and the accessible nitrogen site. In the present work, a nitrogen-rich rth-type metal-organic framework (MOF) was constructed based on rational design and careful synthesis. The MOF presents exceptionally high uptake capacity not only for CO2 but also for H2, which is attributed to favorable interactions between the gas molecules and the nitrogen-rich triazole units of the MOF proved by both experimental measurements and theoretical molecular simulations.

บรรณานุกรม :
Wang, Xiao-Jun , Li, Pei-Zhou , Chen, Yifei , Zhang, Quan , Zhang, Huacheng , Chan, Xiu Xiang , Ganguly, Rakesh , Li, Yongxin , Jiang, Jianwen , Zhao, Yanli . (2556). A rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2 and H2 uptake capability.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Wang, Xiao-Jun , Li, Pei-Zhou , Chen, Yifei , Zhang, Quan , Zhang, Huacheng , Chan, Xiu Xiang , Ganguly, Rakesh , Li, Yongxin , Jiang, Jianwen , Zhao, Yanli . 2556. "A rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2 and H2 uptake capability".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Wang, Xiao-Jun , Li, Pei-Zhou , Chen, Yifei , Zhang, Quan , Zhang, Huacheng , Chan, Xiu Xiang , Ganguly, Rakesh , Li, Yongxin , Jiang, Jianwen , Zhao, Yanli . "A rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2 and H2 uptake capability."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2556. Print.
Wang, Xiao-Jun , Li, Pei-Zhou , Chen, Yifei , Zhang, Quan , Zhang, Huacheng , Chan, Xiu Xiang , Ganguly, Rakesh , Li, Yongxin , Jiang, Jianwen , Zhao, Yanli . A rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2 and H2 uptake capability. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2556.