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Hierarchical layered titanate microspherulite : formation by electrochemical spark discharge spallation and application in aqueous pollutant treatment

หน่วยงาน Nanyang Technological University, Singapore

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ชื่อเรื่อง : Hierarchical layered titanate microspherulite : formation by electrochemical spark discharge spallation and application in aqueous pollutant treatment
นักวิจัย : Tang, Yuxin , Gong, Dangguo , Lai, Yuekun , Shen, Yiqiang , Zhang, Yanyan , Huang, Yizhong , Tao, Jie , Lin, Changjian , Dong, Zhili , Chen, Zhong
คำค้น : DRNTU::Engineering::Materials.
หน่วยงาน : Nanyang Technological University, Singapore
ผู้ร่วมงาน : -
ปีพิมพ์ : 2553
อ้างอิง : Tang, Y., Gong, D., Lai, Y., Shen, Y., Zhang, Y., Hu, Y. et al. (2010). Hierarchical layered titanate microspherulite: formation by electrochemical spark discharge spallation and application in aqueous pollutant treatment. Journal of Materials Chemistry, 20(45). , http://hdl.handle.net/10220/8110 , http://dx.doi.org/10.1039/C0JM02005B
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : Journal of materials chemistry
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

An ultrafast and template-free method to synthesize three-dimensional (3D) hierarchical layered titanate microspherulite (TMS) particles with high surface area is reported. The synthesis makes use of an electrochemical spark discharge spallation (ESDS) process, during which a fast anodic reaction on the titanium surface creates a layer of titanium dioxide that instantly breaks down by the applied electrical field into the solution in the form of titanium oxide particles. The spalled particles readily react with the heated NaOH electrolyte to form the titanate particles. A typical as-prepared TMS with a diameter of 0.4~1.5 μm is synthesized by ESDS of Ti foils in 10 M NaOH solution under an applied current density of 0.5 A cm-2, leading to a reaction yield of approximately 0.10~0.15 g per square centimetre of exposed Ti foil within 20 min. After hydrogen ion exchange, the surface area can reach as high as ~406 m2 g-1. On the Ti surface, a crystalline rutile TiO2 nanosheet structure is formed, which is attributed to the local exothermic heat caused by the spark discharge. A formation mechanism of the TMS is discussed based on field emission scanning electron microscopy (FESEM), a transmission electron microscopy (TEM) study and Raman scattering spectroscopy analysis. The as-prepared TMS shows excellent adsorption performance compared with a titanate micro-particle (TMP), nanowire (TNW) and nanotube (TNT) when methylene blue (MB) and PbII ions are used as representative organic and inorganic pollutants. The mechanism of adsorption has also been discussed.

บรรณานุกรม :
Tang, Yuxin , Gong, Dangguo , Lai, Yuekun , Shen, Yiqiang , Zhang, Yanyan , Huang, Yizhong , Tao, Jie , Lin, Changjian , Dong, Zhili , Chen, Zhong . (2553). Hierarchical layered titanate microspherulite : formation by electrochemical spark discharge spallation and application in aqueous pollutant treatment.
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Tang, Yuxin , Gong, Dangguo , Lai, Yuekun , Shen, Yiqiang , Zhang, Yanyan , Huang, Yizhong , Tao, Jie , Lin, Changjian , Dong, Zhili , Chen, Zhong . 2553. "Hierarchical layered titanate microspherulite : formation by electrochemical spark discharge spallation and application in aqueous pollutant treatment".
    กรุงเทพมหานคร : Nanyang Technological University, Singapore.
Tang, Yuxin , Gong, Dangguo , Lai, Yuekun , Shen, Yiqiang , Zhang, Yanyan , Huang, Yizhong , Tao, Jie , Lin, Changjian , Dong, Zhili , Chen, Zhong . "Hierarchical layered titanate microspherulite : formation by electrochemical spark discharge spallation and application in aqueous pollutant treatment."
    กรุงเทพมหานคร : Nanyang Technological University, Singapore, 2553. Print.
Tang, Yuxin , Gong, Dangguo , Lai, Yuekun , Shen, Yiqiang , Zhang, Yanyan , Huang, Yizhong , Tao, Jie , Lin, Changjian , Dong, Zhili , Chen, Zhong . Hierarchical layered titanate microspherulite : formation by electrochemical spark discharge spallation and application in aqueous pollutant treatment. กรุงเทพมหานคร : Nanyang Technological University, Singapore; 2553.