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Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)- iminomethyl]phenolato-j2N,O1}nickel(II)

หน่วยงาน Universiti Sains Malaysia, Malaysia

รายละเอียด

ชื่อเรื่อง : Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)- iminomethyl]phenolato-j2N,O1}nickel(II)
นักวิจัย : Bahron, Hadariah , Mohd Tajuddin, Amalina , Wan Ibrahim, Wan Nazihah , Fun, Hoong Kun , Chantrapromma, Suchada
คำค้น : QC1-999 Physics
หน่วยงาน : Universiti Sains Malaysia, Malaysia
ผู้ร่วมงาน : -
ปีพิมพ์ : 2557
อ้างอิง : http://eprints.usm.my/38591/1/Crystal_structure_of_bis%7B2%2D[(E)%2D(4%2Dmethoxylbenzyl)%2D.pdf , Bahron, Hadariah and Mohd Tajuddin, Amalina and Wan Ibrahim, Wan Nazihah and Fun, Hoong Kun and Chantrapromma, Suchada (2014) Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)- iminomethyl]phenolato-j2N,O1}nickel(II). Acta Crystallographica Section E: Structure Reports Online, 70. pp. 104-106. ISSN 1600-5368
ที่มา : -
ความเชี่ยวชาญ : -
ความสัมพันธ์ : https://doi.org/10.1107/S160053681401650X , http://eprints.usm.my/38591/
ขอบเขตของเนื้อหา : -
บทคัดย่อ/คำอธิบาย :

The asymmetric unit of the title compound, [Ni(C15H14NO2)2], comprises an NiII cation, lying on an inversion centre, and a Schiff base anion that acts as a bidentate ligand. The NiII cation is in a square-planar coordination environment binding to the imine N and phenolate O atoms of the two Schiff base ligands. The N- and O-donor atoms of the two ligands are mutually trans, with Ni—N and Ni—O bond lengths of 1.9191 (11) and 1.8407 (9) A ° , respectively. The plane of the methoxybenzene ring makes a dihedral angle of 84.92 (6)� with that of the phenolate ring. In the crystal, molecules are linked into screw chains by weak C—H� � �O hydrogen bonds. Additional C—H� � �O hydrogen bonds, together with C—H� � �� contacts, arrange the molecules into sheets parallel to the ac plane.

บรรณานุกรม :
Bahron, Hadariah , Mohd Tajuddin, Amalina , Wan Ibrahim, Wan Nazihah , Fun, Hoong Kun , Chantrapromma, Suchada . (2557). Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)- iminomethyl]phenolato-j2N,O1}nickel(II).
    กรุงเทพมหานคร : Universiti Sains Malaysia, Malaysia.
Bahron, Hadariah , Mohd Tajuddin, Amalina , Wan Ibrahim, Wan Nazihah , Fun, Hoong Kun , Chantrapromma, Suchada . 2557. "Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)- iminomethyl]phenolato-j2N,O1}nickel(II)".
    กรุงเทพมหานคร : Universiti Sains Malaysia, Malaysia.
Bahron, Hadariah , Mohd Tajuddin, Amalina , Wan Ibrahim, Wan Nazihah , Fun, Hoong Kun , Chantrapromma, Suchada . "Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)- iminomethyl]phenolato-j2N,O1}nickel(II)."
    กรุงเทพมหานคร : Universiti Sains Malaysia, Malaysia, 2557. Print.
Bahron, Hadariah , Mohd Tajuddin, Amalina , Wan Ibrahim, Wan Nazihah , Fun, Hoong Kun , Chantrapromma, Suchada . Crystal structure of bis{2-[(E)-(4-methoxylbenzyl)- iminomethyl]phenolato-j2N,O1}nickel(II). กรุงเทพมหานคร : Universiti Sains Malaysia, Malaysia; 2557.